Field ionization mass spectrometry
by
Beckey, Hans-D. (Hans-Dieter)
Title
:
Field ionization mass spectrometry
Author
:
Beckey, Hans-D. (Hans-Dieter)
ISBN
:
9780080175577
9781483160115
Personal Author
:
Beckey, Hans-D. (Hans-Dieter)
Edition
:
1st ed.
Publication Information
:
Oxford ; New York : Pergamon Press, 1971.
Physical Description
:
1 online resource (344 pages) : illustrations.
Series
:
International series of monographs in analytical chemistry ; 42
International series of monographs in analytical chemistry ; 42.
Contents
:
Front Cover; Field Ionization Mass Spectrometry; Copyright Page; Table of Contents; PREFACE; INTRODUCTION; I. PHYSICO-CHEMICAL PROBLEMS; II. PEOBLEMS OF CHEMICAL ANALYSIS; Chapter 1. THEORY OF FIELD IONIZATION (FI) AND FIELD EMISSION (FE); 1.1. FI Probability; 1.2. Particle Supply; 1.3. Minimum Distance for FI; 1.4. Field Electron Emission; Chapter 2. FIELD IONIZATION SOURCES; 2.1. General Design of FI Sources; 2.2. Tips as FI Emitters; 2.3. Thin Wires as FI Emitters; 2.4. Sharp Metal Edges as FI Emitters; 2.5. Comparison of Tips, Thin Wires and Sharp Metal Edges for FI
2.6. Means for Stabilizing Thin Wires During FI2.7. Actual Design of Some FI Sources; 2.8. Pulsed FI Sources; 2.9. FI Microscopes as Sources for Mass Spectrometers; 2.10. Resolving Power of FI Mass Spectrometers; Chapter 3. APPLICATION OF THE FI MASS SPECTROMETER TO PHYSICO-CHEMICAL PROBLEMS; 3.1. Charge Distribution of Organic Ions in High Electric Fields; 3.2. Field Dissociation of Molecular Ions; 3.3. Bond Energies of Molecular Ions; 3.4. Kinetics of Unimolecular Decomposition of Ions in High Electric Fields; 3.5. Temperature Dependence of FI Mass Spectra
3.6. Processes in Adsorbed Layers on FI Emitters3.7. Field-Induced Resonance States at a Surface; 3.8. Isotopie Effects in FI Mass Spectra; 3.9. Negative Ion Emission from Field Emitting Metal Surfaces; Chapter 4. QUALITATIVE ANALYSES WITH THE FI MASS SPECTROMETER; 4.1. FI Mass Spectra of Homologous Series of Organic Substances; 4.2. Detection of Free Radicals by FI Mass Spectrometry; 4.3. Elucidation of Structure, Mechanism and Kinetics of Decomposition of Organic Ions by FI Mass Spectrometry; 4.4. Quantitative Analyses of Mixtures; 5. REFERENCES; INDEX
Abstract
:
Field Ionization Mass Spectrometry focuses on developments in field ionization (FI) mass spectrometry and describes its applications in physical chemistry, with emphasis on mass spectrometric problems. Physico-chemical problems as well as problems of chemical analysis are considered based on issues such as the probability of field ionization; field dissociation and charge distribution; kinetics of ion decomposition in high fields; negative ions; surface diffusion; activation of FI emitters; and elucidation of the structures of organic compounds. This book is comprised of four chapters and beg.
Subject Term
:
Ionization.
Mass spectrometry.
Spectrométrie de masse.
Émission de champ.
Sons -- Spectre.
SCIENCE -- Chemistry -- Analytic.
Ionization. (OCoLC)fst00978621
Mass spectrometry. (OCoLC)fst01011435
Spectrométrie de masse -- méthodes.
Feldionisation (DE-588)4153930-8
Massenspektrometrie (DE-588)4037882-2
Spectroscopie de masse.
Ionisation.
Genre
:
Electronic books.
Electronic Access
:
| Shelf Number | Item Barcode | Shelf Location | Shelf Location | Holding Information |
|---|
| QC454 | 1178706-1001 | Elsevier E-Book Collections | Elsevier E-Book Collections | |