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Advances in organometallic chemistry. Volume 49
Title:
Advances in organometallic chemistry. Volume 49
Author:
West, Robert, 1928-
ISBN:
9780120311491
9781281004826
9786611004828
9780080490366
Publication Information:
Amsterdam : Academic Press, 2003.
Physical Description:
1 online resource (ix, 334 pages) : illustrations.
Series:
Advances in organometallic chemistry ; v. 49
Advances in organometallic chemistry ; v. 49.
Contents:
Front Cover; Advances in Organometallic Chemistry; Copyright Page; Contents; Contributors; Chapter 1. Decamethylsilicocene: Synthesis, Structure, Bonding and Chemistry; I. Introduction; II. Synthesis and Structure of Decamethylsilicocene; III. Bonding in Decamethylsilicocene; IV. Chemistry of Decamethylsilicocene (1); V. Conclusions and Perspectives; References; Chapter 2. Organometallic Phosphorous and Arsenic Betaines; I. Introduction; II. Synthesis of Betaines (+)E15-C-E14-X( -- ) (I) and (+)E15-C-E14( -- ) (II) (E15 = P, As; E14 = Si, Ge, Sn; X = C, S)
III. Structure of Betaines (+)E15-C-E14-X( -- ) I and (+)E15-C-E14( -- ) II According to X-ray DataIV. NMR Parameters of Betaines (+)E15-C-E14-X( -- ) I and (+)P-C-E14( -- ) II; V. Reactivity of Betaines (+)E15-C-E14-X( -- ) I and (+)E15-C-E14( -- ) II (E15 = P, As; E14 Si, Ge, Sn; X = S); VI. Quantum-Chemical Investigation of Potential Energy Surfaces of Betaines (+)E15-C-E14-X( -- ) I and (+)E15-C-E14( -- ) II; VII. Conclusion; References; Chapter 3. Coordination Compounds with Organoantimony and Sbn Ligands; I. Introduction; II. Complexes with R3Sb, R2SbX, AND RSbX2 (R = alkyl, aryl, SiMe3
X = halogen, OR, SR) LigandsIII. Complexes with R2Sb-SbR2 AND R2Sb (R = alkyl, aryl) Ligands; IV. Complexes with R2Sb-Y-SbR2 (R = alkyl, aryl; Y = CH2, O, S) Ligands; V. Complexes with R2Sb-Yn-SbR2 (R = alkyl, aryl; Yn = (SbR)2, 0-C6H4, (CH2)3, S(MeSb)S) Ligands; VI. Complexes with (RSb)n (R = alkyl, aryl) and Sbn Ligands; VII. Concluding Remarks; References; Chapter 4. Ladder Polysilanes; I. Introduction; II. Synthesis; III. Structure; IV. Electronic Properties; V. Reactions; VI. Conclusion; References
Chapter 5. Structure-Reactivity Relationships in the Cyclo-Oligomerization of 1,3-Butadiene Catalyzed by Zerovalent Nickel ComplexesI. Introduction; II. Catalytic Reaction Cycles for the Nickel-Catalyzed Cyclo-Oligomerization of 1,3-Butadiene; III. Computational Models and Methods; IV. Theoretical Exploration of Critical Elementary Reaction Steps; V. Influence of Electronic and Steric Factors on Individual Elementary Steps of the C8-Cyclo-Oligomer Generating Reaction Channel; VI. Theoretically Re.ned Catalytic Cycles for the Nickel-Catalyzed Cyclo-Oligomerization Reactions of 1,3-Butadiene
VII. Regulation of the Cyclo-Oligomer Product SelectivityVIII. Regulation of the C8:C12-Cyclo-Oligomer Product Distribution; IX. Conclusion; References; Chapter 6. Group 13/15 Organometallic Compounds-Synthesis, Structure, Reactivity and Potential Applications; I. Introduction; II. Lewis Acid-Base Adducts; III. Compounds of the Type [R2MER'2]x; IV. Monomers, Heterocycles and Cages of the Type [RMER']x; V. Potential Applications of Group 13/15 Organoelement Compounds in Material Sciences; VI. Conclusions and Outlook; References; Index; Cumulative List of Contributors for Volumes 1-36
Abstract:
Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Volume 49 provides an authorititative, definitive review addressing all aspects of organometallic chemistry. Useful to all researchers within this active field and is a must for every modern library of chemistry. High quality research book within this active field.
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Electronic Access:
ScienceDirect http://www.sciencedirect.com/science/book/9780120311491Available:*
Shelf Number | Item Barcode | Shelf Location | Status |
|---|---|---|---|
| QD411 .A3549 2003 EB | 1181171-1001 | Elsevier E-Book Collections | Searching... |
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