Chapter 1 Total Synthesis of Rk-397total Synthesis of Rk-397 -- Chapter 2 a Formal Total Synthesis of the Marine -- Diterpenoid, Diisocyanoadociane -- Chapter 3 Total Syntheses of Zoapatanol -- Chapter 4 Synthesis of Molecular Tweezers and -- Clips by the Use of a Molecular Lego Set and Their Supramolecular Functions -- Chapter 5 Application of C-glycosides in the Total Synthesis of ( -- )-gambierol -- Chapter 6 a Biomimetic Approach to the Ocaglamides Employing Photogeneration of Oxidopyryliums -- Derived from 3-hydroxyflavones -- Chapter 7 Synthesis Studies of Dolabellanes and Transannular Processes Leading to Related Diterpenes -- Chapter 8 Diphenyloxazinones: Versatile Templates -- for the Asymmetric Synthesis of [alpha]-amino Acids, Peptide Isosteres, and Natural Products -- Chapter 9 Rhodium-catalyzed Cycloisomerization -- Reactions of Allenes in Diversity-oriented -- Synthesis -- Chapter 10 Hydrogen-bond-mediated Organic Synthesis in the Solid State -- Chapter 11 Total Syntheses of Natural Products -- Using the Combined C-h Activation/cope Rearrangement as the Key Step -- Chapter 12 the Total Synthesis of Amphibian -- Alkaloids Using the Intramolecular Schmidt Reaction -- Chapter 13 Seduced by a Sirens Call: Expanding -- Applications for Aromatic Compounds and the Synthesis of (+)-rishirilide B.