Zeolites : a refined tool for designing catalytic sites : proceedings of the International Zeolite Symposium, Québec, Canada, October 15-20, 1995
tarafından
 
International Zeolite Symposium (1995 : Québec, Québec)

Başlık
Zeolites : a refined tool for designing catalytic sites : proceedings of the International Zeolite Symposium, Québec, Canada, October 15-20, 1995

Yazar
International Zeolite Symposium (1995 : Québec, Québec)

ISBN
9780444821300
 
9780080544694
 
9781281984722
 
9786611984724

Toplantı Adı Girişi
International Zeolite Symposium (1995 : Québec, Québec)

Yayın Bilgileri
Amsterdam ; New York : Elsevier, 1995.

Fiziksel Tanımlama
1 online resource (xii, 572 pages) : illustrations.

Seri
Studies in surface science and catalysis ; vol. 97
 
Studies in surface science and catalysis ; 97.

İçerik
Front Cover; Zeolites: A Refined Tool For Designing Catalytic Sites; Copyright Page; Contents; Foreword; Acknowledgements; Chapter 1. One and Two-Dimensional Solid-State NMR Investigations of the Three-Dimensional Structures of Zeolite-Organic Sorbate Complexes; Chapter 2. The Use of Small, Weakly Basic Probe Molecules for the Investigation of Brønsted Acid Sites in Zeolites by NMR Spectroscopy; Chapter 3. Determination of the Environment of Titanium Atoms in TS-1 Silicalite by Ti K-edge X-ray Absorption Spectroscopy, 29Si and 1H Nuclear Magnetic Resonance.

Özet
Formerly, the catalytic use of zeolites was exclusive to the field of acid catalysis. Nowadays, zeolites also find applications as catalysts in a wide array of chemical reactions such as; base catalyzed reactions, Redox reactions and catalytic reactions on transition metals and their complexes in confined environments. The concepts of Brønsted or Lewis acid-base pairs are adequately illustrated in the literature and well-understood in terms of structural and electronic properties of zeolites. By contrast, properties of chemically modified silicates, aluminosilicates and aluminophosphates have not yet been fully explored. The list of oxydo-reduction reactions performed in the presence of these new materials is growing as demonstrated by the selective catalytic reduction of nitrogen oxides or the numerous oxidations employing hydrogen peroxide. Much effort is currently being made to get a better insight into the nature of the sites involved. The zeolite lattice may also be used as a host for encapsulated complexes or metallic clusters allowing the control of nuclearity of these active species and the steric constraints imposed on the reactants. Molecular sieve and shape selectivity effects have also constituted fascinating aspects of zeolite properties. Recent developments leading to increasingly large pore sizes with VPI-5, cloverite and more recently mesoporous molecular sieves have broadened the spectrum of these applications. Indeed, larger and larger reactant and product molecules can be accommodated in these lattices. These new adsorbant/adsorbate systems create additional needs for experimental data and theoretical descriptions of transport properties, in particular of mono- and multi-components diffusion coefficients in the zeolite pore lattice. All these themes, representing the forefront and current trends in zeolite research, were discussed in the submitted papers to the symposium and are widely represented in the selected papers contained in this volume. A feature common to most of these contributions is the combined use of a variety of analytical techniques. Some of these techniques are at the frontier of the latest analytical developments such as multiple scattering EXAFS and bidimensional MAS-NMR.

Konu Başlığı
Zeolites -- Congresses.
 
NATURE -- Rocks & Minerals.
 
SCIENCE -- Earth Sciences -- Mineralogy.
 
Zeolites. (OCoLC)fst01184265
 
Elementos de transicao.
 
Mineralogia.

Tür
Electronic books.
 
Conference papers and proceedings. (OCoLC)fst01423772
 
Conference papers and proceedings.

Added Author
Bonneviot, Laurent.
 
Kaliaguine, S., 1940-

Elektronik Erişim
ScienceDirect http://www.sciencedirect.com/science/book/9780444821300
 
ScienceDirect http://www.sciencedirect.com/science/bookseries/01672991/97


Yer NumarasıDemirbaş NumarasıShelf LocationShelf LocationHolding Information
TP245 .S5 I64 1995 EB1186115-1001Elsevier E-Kitap KoleksiyonuElsevier E-Kitap Koleksiyonu