Sulphones in organic synthesis
Başlık:
Sulphones in organic synthesis
Yazar:
Simpkins, N. S.
ISBN:
9781483292793
Yazar Ek Girişi:
Basım Bilgisi:
1st ed.
Yayın Bilgileri:
Oxford [England] ; New York : Pergamon, 1993.
Fiziksel Tanımlama:
1 online resource (xi, 381 pages) : illustrations
Seri:
Tetrahedron organic chemistry series ; v. 10
Tetrahedron organic chemistry series ; v. 10.
İçerik:
Front Cover; Sulphones in Organic Synthesis; Copyright Page; Preface; Table of Contents; CHAPTER 1. Introduction to Sulphone Chemistry; References; CHAPTER 2. The Preparation of Sulphones; 2.1 Simple Alkyl Aryl and Dialkyl Sulphones; 2.2 Vinyl Sulphones; 2.3 Allylic, Allenic, Alkynyl and Aryl Sulphones; 2.4 Functionalised Sulphones; CHAPTER 3. Sulphonyl Carbanions; 3.1 Introduction to Sulphonyl Carbanions; 3.2 Reactions of Simple Sulphonyl Carbanions; 3.3 Reactions of Additionally Stabilised Sulphonyl Carbanions; 3.4 Sulphonyl Polyanions; CHAPTER 4. Additions to Unsaturated Sulphones.
4.1 Heteroatom Nucleophiles4.2 Non-stabilised Organometallics; 4.3 Enolates, Related Anions and Miscellaneous Carbon Nucleophiles; 4.4 Cyclopropanations; 4.5 Radical Additions; CHAPTER 5. Rearrangements of Sulphones; 5.1 Ring Expansions and Fragmentations; 5.2 Sulphinate to Sulphone Rearrangements; 5.3 1,3-Rearrangements of Allylic Sulphones; 5.4 The Truce-Smiles Rearrangement; 5.5 Miscellaneous Rearrangements; CHAPTER 6. Cycloaddition Chemistry of Unsaturated Sulphones; 6.1 [2+2] Cycloadditions; 6.2 [3+2] Cycloadditions; 6.3 [4+2] Cycloadditions.
CHAPTER 7. Carbon-Carbon Double-Bond Formation by Sulphone Elimination7.1 The Julia Olefination Reaction; 7.2 Alternative ß-Eliminations of Sulphones; 7.3 The Ramberg-Bäcklund Reaction; CHAPTER 8. Chemistry of Cyclic Sulphones; 8.1 Three-membered Ring Sulphones; 8.2 Four-membered Ring Sulphones; 8.3 Five-membered Ring Sulphones; 8.4 Functionalised Normal-sized Rings; 8.5 Larger Ring Sulphones; CHAPTER 9. Desulphonylation; 9.1 Simple Alkyl Aryl and Dialkyl Sulphones; 9.2 Allylic Sulphones; 9.3 Vinyl Sulphones; 9.4 Functionalised Sulphones; 9.5 Sulphone Reduction; INDEX.
Özet:
Over the last twenty years the use of sulphones in organic synthesis has increased dramatically, the synthetic repertoire of sulphones having been developed to such an extent as to rival the carbonyl functionality for versatility. Not only have sulphones been employed in a great many synthetic methodologies, enabling the preparation of a vast array of functionalised products, but the sulphone group has also proved to be of enormous value in many of the most demanding and sophisticated total syntheses carried out in recent years. This book describes in detail all of the important sulphone chemi.
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Elektronik Erişim:
ScienceDirect https://www.sciencedirect.com/science/book/9780080402840 ScienceDirect https://www.sciencedirect.com/science/bookseries/14601567/10Mevcut:*
Yer Numarası | Demirbaş Numarası | Shelf Location | Lokasyon / Statüsü / İade Tarihi |
---|---|---|---|
QD305 .S6 S56 1993 | 1182226-1001 | Elsevier E-Kitap Koleksiyonu | Arıyor... |
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