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Oxidative Dearomatization / Diels-Alder Approaches to Maoecrystal V and the Gibberellin Family of Natural Products
Başlık:
Oxidative Dearomatization / Diels-Alder Approaches to Maoecrystal V and the Gibberellin Family of Natural Products
Yazar:
Smith, Brandon R., author.
ISBN:
9780355942385
Yazar Ek Girişi:
Fiziksel Tanımlama:
1 electronic resource (602 pages)
Genel Not:
Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B.
Advisors: Jon T. Njardarson Committee members: Richard Glass; John Jewett; Dennis L. Lichtenberger.
Özet:
Synthetic approaches to the complex natural product maoecrystal V and the gibberellin family of natural products are presented. The two approaches are united by an oxidative dearomatization / intramolecular Diels Alder strategy for the construction of [2.2.2]-bicyclooctenes. Chapter 1 highlights previous synthetic approaches for the synthesis of maoecrystal V and Chapter 2 chronicles my efforts toward a double-Diels-Alder approach toward maoecrystal V. In the course of investigating a hetero-Diels-Alder strategy for construction of maoecrystal V's tetrahydrofuran ring several fragmentation and rearrangements of the [2.2.2]-bicyclooctene core were encountered. One of these, a novel skeletal rearrangement from [2.2.2] to [3.2.1]-bicyclooctene, was then utilized for entry into the gibberellin family of natural products. Chapter 3 discusses previous syntheses of gibberellins while Chapter 4 details my entry into this family of natural products and further exploration of the novel skeletal rearrangement. Chapter 5 discusses my contributions to the field of bicyclic and tricyclic guanidine synthesis. Finally, Chapter 6 highlights my work related to pharmaceutical drug analysis, focusing on less commonly utilized elemental substitutions.
Notlar:
School code: 0009
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Yer Numarası | Demirbaş Numarası | Shelf Location | Lokasyon / Statüsü / İade Tarihi |
---|---|---|---|
XX(679940.1) | 679940-1001 | Proquest E-Tez Koleksiyonu | Arıyor... |
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