Structure and dynamics of solutions

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Başlık:

Structure and dynamics of solutions

Yazar:

Ohtaki, H.

ISBN:

9781483291420

Yayın Bilgileri:

Amsterdam ; New York : Elsevier, 1992.

Fiziksel Tanımlama:

1 online resource (xv, 344 pages) : illustrations.

Seri:

Studies in physical and theoretical chemistry ; 79

Studies in physical and theoretical chemistry ; 79.

İçerik:

Front Cover; Structure and Dynamics of Solutions; Copyright Page; Preface; List of Contributors; Table of Contents; Chapter 1. Introduction; Chapter 2. Structure of Solutions by Diffraction, EXAFS, and XANES Methods; 2.1 Apparatus Used for X-Ray and Neutron Diffraction and for EXAFS and XANES Measurements; 2.2 Structure of Liquids and Solutions by X-Ray and Neutron Diffraction; 2.3 Structure of Solvated Ions and Metal Complexes in Solution Studied by the Diffraction Method; 2.4 Structure of Metal Complexes in Solution by the EXAFS and XANES Methods; References

Chapter 3. Molecular Dynamics Simulations of Liquids and Solutions3.1 Computer Experiments; 3.2 Local Composition in Lennard-Jones Mixtures; 3.3 Computer Simulations of Fluid Water and Its Liquid-Gas Interface with Carravetta-Clementi Potential; 3.4 Hydration in Dilute Aqueous Solution of Nonelectrolytes; 3.5 The Structure of Hydrated Ions in Aqueous Solutions as Studied by the Molecular Dynamics Simulations; 3.6 Molecular Dynamics Studies on Electric Conductivity of Ionic; REFERENCES; Chapter 4. Dynamic Properties of Liquids and Solutions; 4.1 Dynamic Properties of Ions in Solutions

4.2 Dynamics of Ions and Solvent Molecules in Solution -Nuclear Magnetic Relaxation Studies4.3 Association of Alkylammonium Salts in Nonaqueous Solvents; 4.4 Water and Metal Ions at Water-Amphiphile Interfaces; REFERENCES; Chapter 5. Effects of Pressure and Temperature; 5.1 Pressure and Temperature Effects on Irreversible Processes in Solution; 5.2 Some New Apparatus; 5.3 Molecular Conformation in Solution; REFERENCES; Chapter 6. Ion-Ion and Ion-Solvent Interactions and Complex Formation in Solution; 6.1 Solvent Properties and Reactions in Solution

6.2 Solute-Solvent Interactions of Metal Chelate Electrolytes6.3 Reaction and Activation Volumes for Some Reactions Involving Metal Complexes in Solution; 6.4 Ion-Triplets as the Precursor for Electron Transfer Reactions of Coordination Compounds; 6.5 Mechanism of Sulfur-Inversion in Platinum(II)-Thioether Complexes Revisited; REFERENCES; Chapter 7. Energetic Aspects on Solute-Solvent Interactions; 7.1 Thermodynamic Aspects of Complex Formation Reactions in Nonaqueous Solutions; 7.2 Statistical Mechanical Approaches to the Structure and Thermodynamic Properties of Solutions

7.3 Electronic States of Ions and Molecules in Solution Studied by Photoelectron Emission SpectroscopyREFERENCES; Concluding Remarks; Subject Index

Özet:

Recent advances in the study of structural and dynamic properties of solutions have provided a molecular picture of solute-solvent interactions. Although the study of thermodynamic as well as electronic properties of solutions have played a role in the development of research on the rate and mechanism of chemical reactions, such macroscopic and microscopic properties are insufficient for a deeper understanding of fast chemical and biological reactions. In order to fill the gap between the two extremes, it is necessary to know how molecules are arranged in solution and how they change their pos.

Konu Başlığı:

Solution (Chemistry)

Solution (Chemistry) (OCoLC)fst01125636

Solutions (chimie)

Elektrolytlösung (DE-588)4133913-7

Flüssigkeit (DE-588)4017621-6

Lösung.

Theoretische Chemie (DE-588)4185098-1

Tür:

Electronic books.

Added Author:

Ohtaki, H.