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Interfacial Interactions in 2D Materials and Related Molecular Networks
Başlık:
Interfacial Interactions in 2D Materials and Related Molecular Networks
Yazar:
Sun, Chao, author. (orcid)0000-0002-0542-5935
ISBN:
9780438026124
Yazar Ek Girişi:
Fiziksel Tanımlama:
1 electronic resource (209 pages)
Genel Not:
Source: Dissertation Abstracts International, Volume: 79-10(E), Section: B.
Includes supplementary digital materials.
Advisors: William R. Dichtel Committee members: Brian Crane; Paul L. McEuen.
Özet:
Since the first report of monolayer graphene in 2004, macromolecules that exhibit sheet-like topology including two-dimensional (2D) materials and related molecular networks have promised a wealth of intrigue in both fundamental science and technology. 2D gives rise to important interfacial behavior including molecular absorption, adhesion, cohesion, and bio-interfacing during materials' synthesis, processing, and applications. This dissertation focuses on molecular mechanisms governing the interfacial behavior of 2D materials and related molecular analogs. Chapter 1 provides an overview of the interfacial molecular mechanisms used for 2D macromolecules. Chapter 2 looks into the detailed mechanisms and control of functional molecules' absorption on graphene oxide (GO) nanosheets. Chapter 3 builds a tool to understand how surface organic monolayers manipulate the adhesion of graphene. Chapter 4 explores reversible cohesive mechanisms in 2D synthetic networks using macrocyclic analogs that stack into high aspect ratio, lyotropic nanotubes. This dissertation ends with a complex interface between GO and cell surfaces in Chapter 5 to discuss how GO nanosheets stimulate biological cells and find potential in cancer therapeutics. These results empower adhesive engineering, stacking control, and therapeutics design of 2D materials and related molecular networks.
Notlar:
School code: 0058
Tüzel Kişi Ek Girişi:
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Yer Numarası | Demirbaş Numarası | Shelf Location | Lokasyon / Statüsü / İade Tarihi |
---|---|---|---|
XX(680262.1) | 680262-1001 | Proquest E-Tez Koleksiyonu | Arıyor... |
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